Theoretical investigation on the Cu(i)-catalyzed N-carboxamidation of indoles with isocyanates to form indole-1-carboxamides: effects of solvents-Reference-Cited by-同舟云学术

Theoretical investigation on the Cu(i)-catalyzed N-carboxamidation of indoles with isocyanates to form indole-1-carboxamides: effects of solvents

Published:2020 Issue:23 Volume:44 Page:9878-9887
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Yuan Binfang¹²³⁴⁵^ORCID,Wan Jingwei⁶⁷⁸⁵,Guo Xiaogang¹²³⁴⁵,Gong Yongmi¹²³⁴⁵,Zhang Fulan¹²³⁴⁵,Li Qing¹²³⁴⁵,Wang Guangzhao⁹¹⁰¹¹³⁴,Chen Jinyang¹²³⁴⁵^ORCID,He Rongxing²¹²¹³⁵^ORCID

Affiliation:

1. Chongqing Key Laboratory of Inorganic Special Functional Materials

2. College of Chemistry and Chemical Engineering

3. Yangtze Normal University

4. Chongqing 408100

5. China

6. Department of Criminal Science and Technology

7. Railway Police College

8. Zhengzhou

9. Key Laboratory of Micro Nano Optoelectronic Devices and Intelligent Perception Systems

10. Key Laboratory of Extraordinary Bond Engineering and Advanced Materials Technology of Chongqing

11. School of Electronic Information Engineering

12. Southwest University

13. Chongqing 400715

Abstract

The solvents act as the hydrogen-bond acceptor to facilitate intermolecular addition, and then play the proton-shuttle to assist H1⁺-shift. The stronger electron-donating property of solvent is favorable for the present Cu(i)-catalyzed reactions.

Funder

Chongqing Municipal Education Commission Foundation

Chongqing Science and Technology Commission

National Natural Science Foundation of China

Yangtze University

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/NJ/D0NJ01116A

Reference62 articles.