A [C1 + C2] route to propargylidyne complexes
Author:
Affiliation:
1. Research School of Chemistry
2. The Australian National University
3. Canberra
4. Australia
Abstract
The reactions of [W(CBr)(CO)2(Tp*)] with a range of terminal alkynes (RCCH), mediated by [Pd(PPh3)4] and CuI, afford new propargylidynes [W(C–CCR)(CO)2(Tp*)] [R = tBu, C6H4X (X = H, NH2, NO2), APh3 (A = C, Si, Ge), B(O2CCH2)2NMe].
Funder
Australian Research Council
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT00876D
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