Photochlorination of toluene – the thin line between intensification and selectivity. Part 2: selectivity-Reference-Cited by-同舟云学术

Photochlorination of toluene – the thin line between intensification and selectivity. Part 2: selectivity

Published:2021 Issue:1 Volume:6 Page:90-99
ISSN:2058-9883
Container-title:Reaction Chemistry & Engineering
language:en
Short-container-title:React. Chem. Eng.

Author:

Taştan Ümit¹²³⁴^ORCID,Seeber Phillip¹²³⁴^ORCID,Kupfer Stephan⁵⁶⁷⁴^ORCID,Ziegenbalg Dirk¹²³⁴^ORCID

Affiliation:

1. Institute of Chemical Engineering

2. Ulm University

3. 89081 Ulm

4. Germany

5. Institut für Physikalische Chemie

6. Friedrich-Schiller-Universität Jena

7. 07743 Jena

Abstract

The selectivity of the photochlorination of toluene was found to decrease under intensified conditions. This was traced back to the formation of a toluene–chlorine complex, that activates the ring upon irradiation and causes ring chlorination.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Fluid Flow and Transfer Processes,Process Chemistry and Technology,Chemical Engineering (miscellaneous),Chemistry (miscellaneous),Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/RE/D0RE00366B

Reference41 articles.

1. Photochlorination of toluene – the thin line between intensification and selectivity. Part 1: intensification and effect of operation conditions

2. INEOS AG , INCH Magazine , 2014 , vol. 7 , p. 30

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