Catalyst-free synthesis of 3,1-benzoxathiin-4-ones/1,3-benzodioxin-4-ones

Author:

Muthusamy Sengodagounder1234ORCID,Malarvizhi Muthukumar1234ORCID,Suresh Eringathodi5674ORCID

Affiliation:

1. School of Chemistry

2. Bharathidasan University

3. Tiruchirappalli-620 024

4. India

5. Analytical Discipline and Centralized Instrumentation Facility

6. Central Salt & Marine Chemicals Research Institute

7. Bhavnagar-364 002

Abstract

An unambiguous and precise method for the synthesis of 3,1-benzoxathiin-4-ones/1,3-benzodioxin-4-ones by the reaction of propargylic alcohols and salicylic/thiosalicylic acids under a catalyst-free and open-air atmosphere is described.

Funder

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference29 articles.

1. E. Kleinpeter and M.Sefkow , 1,3-Dioxins, Oxathiins, Dithiins and their Benzo Derivatives , in Compr. Heterocycl. Chem. II , Pergamon Press , Amsterdam , 2008 , vol. 8 , pp. 739–856

2. T. Kunied and H.Mutsanga , in The Chemistry of Heterocyclic Compounds , Academic Press , Palmer , 2002 , pp. 175

3. Addition of thiobenzophenone to benzenediazonium-2-carboxylate

4. A novel cyclization reaction of o-carboxyphenyl and o-carbamoylphenyl sulfoxides

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