Interaction of germanium analogue of organic isonitrile with Cu(<scp>i</scp>) imide in side-on mode-Reference-Cited by-同舟云学术

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Interaction of germanium analogue of organic isonitrile with Cu(i) imide in side-on mode

Published:2023 Issue:31 Volume:52 Page:10672-10676
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Huo Shuai-Cong¹,Li Yao¹,Ji Peng-Fei¹,Zhang De-Xiang¹,Yang Ying¹^ORCID,Roesky Herbert W.²^ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering, Central South University, Lushannan Road 932, 410083 Changsha, China

2. Institut für Anorganische Chemie, Universität Göttingen, Tammannstrasse 4, 37077 Göttingen, Germany

Abstract

[NHC → GeN(Ar)Cu2NAr]2, the formal adduct of germanium analogue of organic isonitrile [GeNAr] with Cu(i) imide [(Cu2NAr)2] (Ar = 2,6-iPr2C6H3) was prepared and shown to adopt a side-on mode of interaction.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT02094K

Reference27 articles.

1. Synthesis and structural characterization of the cyclic species [GeN(2,6-iso-Pr2C6H3)]3: the first "germanazene"

2. Imide Transfer Properties and Reactions of the Magnesium Imide ((THF)MgNPh)6: A Versatile Synthetic Reagent

3. Unsaturated Molecules Containing Main Group Metals

4. Facile synthesis of Sn4N4 cubanes; syntheses and structures of [Sn(NC6H11)]4 and [Sn(2-NCH2C5H4N)]4

5. Synthesis and structural and spectroscopic characterization of the Germanazene [GeN(2,6-i-Pr2C6H3)]3 and the tin and lead tetramers [SnN(BMes2)]4, [SnN(2,6-i-Pr2C6H3)]4, and [PbN(2,6-i-Pr2C6H3)]4

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