Synthesis, structure and magnetic properties of two bis(oxalato)cuprate(ii) salts with pyridinium type counter ions

Author:

Dazem Cyrielle L. F.1,Inge A. Ken2ORCID,Luneau Dominique3ORCID,Öhrström Lars4ORCID,Nenwa Justin1

Affiliation:

1. Inorganic Chemistry Department, Faculty of Science, University of Yaoundé I, PO. Box 812, Yaoundé, Cameroon

2. Department of Materials and Environmental Chemistry, Stockholm University, Stockholm, SE-106 91 Sweden

3. Laboratoire des Multimatériaux et Interfaces (UMR 5615), Université Claude Bernard de Lyon 1, Campus de la Doua, 69622 Villeurbanne, France

4. Chemistry and Biochemistry, Dept. of Chemistry and Chemical Engineering, Chalmers University of Technology, SE-41296 Göteborg, Sweden

Abstract

In the Cu(ii) oxalate salts of (C5H7N2O)2[Cu(C2O4)2] 1 and C13H16N2[Cu(C2O4)2] 2, the oxalate adopts different coordination modes: the common bidentate chelating oxalate in 1 and the relatively scarce μ-oxalato-κ3O1,O2:O1′ in 2.

Funder

Stiftelsen Olle Engkvist Byggmästare

Vetenskapsrådet

Stiftelsen för Strategisk Forskning

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Reference38 articles.

1. L.Öhrström and J.Covès , The Rhubarb Connection and Other Revelations: The Everyday World of Metal Ions, https://pubs.rsc.org/en/content/ebook/978-1-78801-094-8 , Royal Society of Chemistry, London, 2018

2. Natural and synthetic metal oxalates – a topology approach

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4. Adjusting Rotational Behavior of Molecular Rotors by a Rational Tuning of Molecular Structure

5. Triazole-assisted trinuclear oxidovanadium(IV) complexes for gas adsorptions

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