Rh(ii)-Catalyzed denitrogenative 1-sulfonyl-1,2,3-triazole-1-alkyl-1,2,3-triazole cross-coupling as a route to 3-sulfonamido-1H-pyrroles and 1,2,3-triazol-3-ium ylides-Reference-Cited by-同舟云学术

Rh(ii)-Catalyzed denitrogenative 1-sulfonyl-1,2,3-triazole-1-alkyl-1,2,3-triazole cross-coupling as a route to 3-sulfonamido-1H-pyrroles and 1,2,3-triazol-3-ium ylides

Published:2021 Issue:7 Volume:8 Page:1474-1481
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Koronatov Alexander N.¹²³⁴^ORCID,Afanaseva Kseniia K.¹²³⁴,Sakharov Pavel A.¹²³⁴^ORCID,Rostovskii Nikolai V.¹²³⁴^ORCID,Khlebnikov Alexander F.¹²³⁴^ORCID,Novikov Mikhail S.¹²³⁴^ORCID

Affiliation:

1. St Petersburg State University

2. Institute of Chemistry

3. St Petersburg

4. Russia

Abstract

The reaction of 1-alkyl-1H-1,2,3-triazoles with rhodium(ii) azavinyl carbenes, generated from 1-sulfonyl-1H-1,2,3-triazoles, was utilized to prepare 3-sulfonamido-1H-pyrroles and 1,2,3-triazol-3-ium ylides in good yields.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/QO/D0QO01571G

Reference80 articles.

1. Sulfonyl-1,2,3-Triazoles: Convenient Synthones for Heterocyclic Compounds

2. Aryl(sulfonyl)amino Group: A Convenient and Stable Yet Activated Modification of Amino Group for Its Intramolecular Displacement

3. Synthetic and mechanistic aspects of sulfonyl migrations