Intramolecular dearomative 1,4-addition of silyl and germyl radicals to a phenyl moiety-Reference-Cited by-同舟云学术

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Intramolecular dearomative 1,4-addition of silyl and germyl radicals to a phenyl moiety

Published:2024 Issue:7 Volume:53 Page:2917-2921
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Krämer Felix¹^ORCID,Wenzel Jonas O.¹^ORCID,Fernández Israel²^ORCID,Breher Frank¹^ORCID

Affiliation:

1. Institute of Inorganic Chemistry, Karlsruhe Institute of Technology (KIT), Engesserstr. 15, 76131 Karlsruhe, Germany

2. Departamento de Química Orgánica I, Facultad de Ciencias Químicas and Centro de Innovación en Química Avanzada (ORFEO-CINQA), Universidad Complutense de Madrid, 28040 Madrid, Spain

Abstract

Ylide-functionalised radicals: Tetryl radicals 2Si and 2Ge can be generated by reduction of suitable ylide-functionalised precursors and undergo instant cyclization reaction with a phenyl moiety, which is rarely found in the case of germyl radicals.

Funder

Agencia Estatal de Investigación

Verband der Chemischen Industrie

Ministerio de Ciencia e Innovación

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT00089G

Reference39 articles.

1. Triphenylmethyl, ein Fall von dreiwerthigem Kohlenstoff

2. Preparation and Properties of Hexaaryldisilanes

3. Analogs of Hexaphenylethane. IV. Hexaphenyldigermane1

4. Investigations on organolead compounds VII. The preparation of hexaaryldileads

5. Erste reversible thermische Dissoziation von Distannanen R3Sn-SnR3 zu Stannylradikalen R3Sn.

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