Boosting of overall water splitting activity by regulating the electron distribution over the active sites of Ce doped NiCo–LDH and atomic level understanding of the catalyst by DFT study-Reference-Cited by-同舟云学术

Boosting of overall water splitting activity by regulating the electron distribution over the active sites of Ce doped NiCo–LDH and atomic level understanding of the catalyst by DFT study

Published:2022 Issue:34 Volume:10 Page:17488-17500
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Dhandapani Hariharan N.¹²^ORCID,Mahendiran D.¹³^ORCID,Karmakar Arun¹²^ORCID,Devi Pandiarajan¹³^ORCID,Nagappan Sreenivasan¹²,Madhu Ragunath¹²^ORCID,Bera Krishnendu¹²^ORCID,Murugan Palanichamy¹³^ORCID,Babu B. Ramesh¹²^ORCID,Kundu Subrata¹²^ORCID

Affiliation:

1. Academy of Scientific and Innovative Research (AcSIR), Ghaziabad-201002, India

2. Electrochemical Process Engineering (EPE) Division, CSIR-Central Electrochemical Research Institute (CECRI), Karaikudi-630003, Tamil Nadu, India

3. Electrochemical Power Sources (ECPS) Division, CSIR-Central Electrochemical Research Institute (CECRI), Karaikudi-630003, Tamil Nadu, India

Abstract

Ce3+ ion doped NiCoLDHs have applied as a promising electrocatalysts for water splitting. 9.715 times high TOF has observed as a result of Ce doping. DFT study shows that Co-3d states are highly responsible for catalytic activity of the catalyst.

Funder

Central ElectroChemical Research Institute

Council of Scientific and Industrial Research, India

University Grants Commission

Department of Science and Technology, Ministry of Science and Technology, India

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/TA/D2TA04647D

Reference54 articles.