Direct synthesis of an anionic 13-vertex closo-cobaltacarborane cluster-Reference-Cited by-同舟云学术

Direct synthesis of an anionic 13-vertex closo-cobaltacarborane cluster

Published:2019 Issue:42 Volume:48 Page:15772-15777
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Maier Thomas M.¹²³⁴^ORCID,Coburger Peter¹²³⁴⁵^ORCID,van Leest Nicolaas P.⁶⁷⁸⁹^ORCID,Hey-Hawkins Evamarie⁵²¹⁰⁴^ORCID,Wolf Robert¹²³⁴^ORCID

Affiliation:

1. University of Regensburg

2. Institute of Inorganic Chemistry

3. 93040 Regensburg

4. Germany

5. Leipzig University

6. Van't Hoff Institute for Molecular Sciences (HIMS)

7. University of Amsterdam (UvA) Science Park 904

8. 1098 XH Amsterdam

9. The Netherlands

10. 04103 Leipzig

Abstract

Reaction of 1,2-bis(diphenylphosphino)-ortho-carborane (L) with [K(thf){(^MesBIAN)Co(η⁴-cod)}] (1, ^MesBIAN = bis(mesityliminoacenaphthene)diimine, cod = 1,5-cyclooctadiene) affords an anionic 13-vertex closo-cobaltacarborane cluster (2) in one step.

Funder

Universität Leipzig

Studienstiftung des Deutschen Volkes

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT03111A

Reference51 articles.

1. Metallacarboranes in the new millennium

2. R. N. Grimes , Carboranes , Elsevier , Saint Louis , 3rd edn, 2016