Sticking and patching: tuning and anchoring cyclometallated ruthenium(ii) complexes

Author:

Ertl Cathrin D.1234,Ris Daniel P.1234,Meier Stefan C.5678,Constable Edwin C.1234,Housecroft Catherine E.1234,Neuburger Markus1234,Zampese Jennifer A.1234

Affiliation:

1. Department of Chemistry

2. University of Basel

3. 4056 Basel

4. Switzerland

5. Institut für Anorganische und Analytische Chemie

6. Albert-Ludwigs-Universität

7. D-79104 Freiburg i. Br.

8. Germany

Abstract

In a series of [Ru(bpy)2(C^N)][PF6] complexes with a variety of functionalities in the cyclometallating ligand, the absorption response is enhanced considerably by the introduction of a 4-C6H4P(O)(OEt)2 anchoring domain in the C^N pyridine ring.

Funder

European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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