Mechanistic insights into dehydrocoupling of amine boranes using dinuclear zirconocene complexes-Reference-Cited by-同舟云学术

Mechanistic insights into dehydrocoupling of amine boranes using dinuclear zirconocene complexes

Published:2021 Issue:12 Volume:11 Page:4034-4050
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Lindenau Kevin¹²³,Jannsen Nora¹²³,Rippke Mirko¹²³,Al Hamwi Hanan¹²³,Selle Carmen¹²³,Drexler Hans-Joachim¹²³,Spannenberg Anke¹²³,Sawall Mathias⁴⁵⁶³,Neymeyr Klaus¹²³⁴⁵^ORCID,Heller Detlef¹²³,Reiß Fabian¹²³^ORCID,Beweries Torsten¹²³^ORCID

Affiliation:

1. Leibniz-Institut für Katalyse e.V

2. 18059 Rostock

3. Germany

4. Institut für Mathematik

5. Universität Rostock

6. 18055 Rostock

Abstract

Catalytic dehydrocoupling of H₃B·NMe₂H using Cp₂Zr(Cl)(μ-Me₃SiC₃SiMe₃)Zr(Cl)Cp₂ (1)/MeLi was studied. Spectroscopic monitoring and stoichiometric experiments show the formation and interconversion of several catalytically active Zr species.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CY/D1CY00531F

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