Non-symmetrical diarylcarboxylic acids via rhodium(i)-catalyzed regiospecific cross-dehydrogenation coupling of aromatic acids: twofold direct C–H bond activations in water-Reference-Cited by-同舟云学术

Non-symmetrical diarylcarboxylic acids via rhodium(i)-catalyzed regiospecific cross-dehydrogenation coupling of aromatic acids: twofold direct C–H bond activations in water

Published:2016 Issue:94 Volume:6 Page:91617-91620
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Zhang Hailong¹²³⁴⁵,Deng Guo-Jun¹²³⁴⁵,Li Shiguang¹²³⁴⁵,Li Chao-Jun⁶⁷⁸⁹¹⁰,Gong Hang¹²³⁴⁵

Affiliation:

1. The Key Laboratory of Environmentally Friendly Chemistry and Application of the Ministry of Education

2. College of Chemistry

3. Xiangtan University

4. Xiangtan 411105

5. China

6. Department of Chemistry

7. FQRNT Centre for Green Chemistry and Catalysis

8. McGill University

9. W. Montreal

10. Canada

Abstract

An efficient, regiospecific, and general cross-dehydrogenative coupling reaction of free aryl acids to generate non-symmetrical diaryl acids was developed. This strategy involves a two fold direct C–H activation catalyzed by rhodium in water, and can be easily scaled up.

Funder

Canada Foundation for Innovation

Canada Research Chairs

Fonds Québécois de la Recherche sur la Nature et les Technologies

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA21185B

Reference41 articles.

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