Polymorph transformation in a mixed-stacking nickel-dithiolene complex with the derivative of 4,4′-bipyridinium-Reference-Cited by-同舟云学术

Polymorph transformation in a mixed-stacking nickel-dithiolene complex with the derivative of 4,4′-bipyridinium

Published:2024 Issue:19 Volume:53 Page:8202-8213
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Gao Yan¹,Xu Lei¹,Feng Zi-Heng¹,Qian Yin¹^ORCID,Tian Zheng-Fang²^ORCID,Ren Xiao-Ming¹³^ORCID

Affiliation:

1. State Key Laboratory of Materials-Oriented Chemical Engineering and College of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, P. R. China

2. Hubei Key Laboratory of Processing and Application of Catalytic Materials, Huanggang Normal University, Huanggang, 438000, P. R. China

3. State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, P. R. China

Abstract

Two polymorphs of 1 manifesting in dark-green (1-g) and red hues (1-r) demonstrate thermochromism. 1-g undergoes transformation to 1-r via solvent-induced and grinding methods, while the reverse occurs through thermal annealing.

Funder

Priority Academic Program Development of Jiangsu Higher Education Institutions

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT00324A

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5. Disorder–Order Transformation and Significant Dislocation Motion Cooperating with a Surprisingly Large Hysteretic Magnetic Transition in a Nickel–Bisdithiolene Spin System