Hydroxamate-directed access to β-Kdo glycosides-Reference-Cited by-同舟云学术

Hydroxamate-directed access to β-Kdo glycosides

Published:2023 Issue:66 Volume:59 Page:10028-10031
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Pramanik Sourav¹,Mondal Soumik¹,Chinarev Alexander²^ORCID,Bovin Nicolai V.²,Saha Jaideep³^ORCID

Affiliation:

1. Department of Biological and Synthetic Chemistry, Centre of Biomedical Research (CBMR), Lucknow 226014, India

2. Shemyakin-Ovchinnikov Institute of Bioorganic Chemistry of the Russian Academy of Sciences, Moscow 117997, Russia

3. Department of Medicinal Chemistry, National Institute of Pharmaceutical Education and Research (NIPER), Mohali 160062, India

Abstract

The manifold leading to aziridinone or azaoxyallyl cation, when incorporated at anomeric centre of Kdo-glycosyl donor, stereoselective glycosylation was achieved leading to β-Kdo glycosides. Pivotal roles of hydroxamate over amide is revealed in control experiments.

Funder

Science and Engineering Research Board

Department of Science and Technology, Ministry of Science and Technology, India

Council of Scientific and Industrial Research, India

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D3CC02609D

Reference31 articles.

1. Kdo: a critical monosaccharide for bacteria viability

2. The Chemistry and Biological Significance of 3-Deoxy-d-manno-2-Octulosonic Acid (KDO)

3. Lipopolysaccharide Endotoxins

4. Biosynthesis and Assembly of Capsular Polysaccharides in Escherichia coli

5. KpsC and KpsS are retaining 3-deoxy-D-manno-oct-2-ulosonic acid (Kdo) transferases involved in synthesis of bacterial capsules

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