Redox-induced Diels–Alder revisited: impact of diene's oxidation on demanding cycloadditions-Reference-Cited by-同舟云学术

Redox-induced Diels–Alder revisited: impact of diene's oxidation on demanding cycloadditions

Published:2023 Issue:22 Volume:10 Page:5637-5643
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Jadwiszczak Michał J.¹,Leszczyński Piotr J.¹,Mazej Zoran²^ORCID,Malinowski Przemysław J.¹^ORCID,Nawrocka Ewa K.¹^ORCID,Kazimierczuk Krzysztof¹^ORCID,Kwiatkowski Piotr³^ORCID,Połczyński Piotr³,Grochowska-Tatarczak Magdalena¹,Fijalkowski Karol J.¹^ORCID,Sadło Jarosław⁴^ORCID,Grochala Wojciech¹^ORCID

Affiliation:

1. Center of New Technologies, University of Warsaw, Banacha 2c, 02-093 Warsaw, Poland

2. Department of Inorganic Chemistry and Technology, Jožef Stefan Institute, Jamova cesta 39, 1000 Ljubljana, Slovenia

3. Faculty of Chemistry, University of Warsaw, Pasteur 1, 02-093 Warsaw, Poland

4. Centre for Radiation Research and Technology, Institute of Nuclear Chemistry and Technology, Dorodna 16, 03-195 Warsaw, Poland

Abstract

Our proposition for the modification is:In opposition to the classical explanation of reactivity in Diels–Alder reactions, they can be facilitated by oxidation of dienes with the use of AgIISO4. Experimental and computational studies show the potential and bottlenecks of redox-initiated DA.

Funder

Narodowe Centrum Nauki

Javna Agencija za Raziskovalno Dejavnost RS

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QO/D3QO00985H

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