Impact of the hybridization form of the coordinated nitrogen atom on the electrocatalytic water oxidation performance of copper complexes with pentadentate amine-pyridine ligands

Author:

Yu Kaishan12,Wang Tao1,Sun Yue1,Kang Mei1,Wang Xinxin1,Zhu Dingwei1,Xue Siyi1,Shen Junyu1ORCID,Zhang Qijian1ORCID,Liu Jinxuan12ORCID

Affiliation:

1. Jiangsu Laboratory of Advanced Functional Materials, School of Materials Engineering, Changshu Institute of Technology, Changshu 215500, P. R. China

2. State Key Laboratory of Fine Chemicals, Dalian University of Technology (DUT), Dalian 116024, P. R. China

Abstract

Pyridine group in the ligand is beneficial to reducing the overpotential and improving the stability of copper complexes used as catalysts for OER, while the amino group is advantageous to enhancing catalytic activity.

Funder

National Natural Science Foundation of China

Postdoctoral Science Foundation of Jiangsu Province

China Postdoctoral Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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