A magnetic look into the protecting layer of Au25 clusters-Reference-Cited by-同舟云学术

A magnetic look into the protecting layer of Au25 clusters

Published:2016 Issue:12 Volume:7 Page:6910-6918
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Agrachev Mikhail¹²³⁴,Antonello Sabrina¹²³⁴,Dainese Tiziano¹²³⁴,Gascón José A.¹⁵⁶,Pan Fangfang¹⁷⁸⁹¹⁰,Rissanen Kari¹⁷⁸⁹¹⁰,Ruzzi Marco¹²³⁴,Venzo Alfonso¹¹¹²²³⁴,Zoleo Alfonso¹²³⁴,Maran Flavio¹²³⁴¹

Affiliation:

1. Department of Chemistry

2. University of Padova

3. 35131 Padova

4. Italy

5. University of Connecticut

6. USA

7. Nanoscience Center

8. University of Jyväskylä

9. 40014 JYU

10. Finland

11. National Research Council

12. ICMATE c/o Department of Chemistry

Abstract

We prepared four structurally related paramagnetic Au₂₅(SR)018 clusters. ¹H ENDOR and NMR signals could be successfully related to the types of ligand and the distance of protons from the central gold core. It is shown that the unpaired electron can be used as a very precise probe of the structure of the interface between metal core and capping ligands.

Funder

AIRC

Academy of Finland

University of Connecticut

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/SC/C6SC03691K

Reference42 articles.

1. The Story of a Monodisperse Gold Nanoparticle: Au25L18