Reduction of Np(<scp>vi</scp>) with hydrazinopropionitrile <i>via</i> water-mediated proton transfer-Reference-Cited by-同舟云学术

Reduction of Np(vi) with hydrazinopropionitrile via water-mediated proton transfer

Published:2022 Issue:29 Volume:24 Page:17782-17791
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Li Xiao-Bo¹²,Wu Qun-Yan¹^ORCID,Wang Cong-Zhi¹,Lan Jian-Hui¹,Zhang Meng²^ORCID,Gibson John K.³^ORCID,Chai Zhi-Fang¹,Shi Wei-Qun¹^ORCID

Affiliation:

1. Laboratory of Nuclear Energy Chemistry, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China

2. Fundamental Science on Nuclear Safety and Simulation Technology Laboratory, College of Nuclear Science and Technology, Harbin Engineering University, Harbin, Heilongjiang, 150001, China

3. Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California, 94720, USA

Abstract

The reduction mechanisms of Np(vi) with hydrazinopropionitrile were theoretically explored and the pathway with water-mediated proton transfer is energetically preferred.

Funder

National Natural Science Foundation of China

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D2CP01730J

Reference81 articles.

1. Z.Yoshida , S. G.Johnson , T.Kimura and J. R.Krsul , The Chemistry of the Actinide and Transactinide Elements , Springer Netherlands , Dordrecht , 2006 , pp. 699–812

2. P. D.Wilson , The Nuclear Fuel Cycle: From Ore to Waste , Oxford University Press , United Kingdom , 1996

3. Progress towards the Full Recovery of Neptunium in an Advanced PUREX Process

4. The reduction of plutonium and neptunium ions by acetaldoxime in nitric acid

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