Photolytic splitting of homodimeric quinone-derived oxetanes studied by ultrafast transient absorption spectroscopy and quantum chemistry-Reference-Cited by-同舟云学术

Photolytic splitting of homodimeric quinone-derived oxetanes studied by ultrafast transient absorption spectroscopy and quantum chemistry

Published:2024 Issue:17 Volume:26 Page:13489-13496
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Blasco-Brusola Alejandro¹,Tamarit Lorena¹^ORCID,Navarrete-Miguel Miriam²,Roca-Sanjuán Daniel²^ORCID,Miranda Miguel A.¹^ORCID,Vayá Ignacio¹^ORCID

Affiliation:

1. Departamento de Química/Instituto de Tecnología Química UPV-CSIC, Universitat Politècnica de València, Camino de Vera s/n, València 46022, Spain

2. Instituto de Ciencia Molecular, Universitat de València, P.O. Box 22085, València 46071, Spain

Abstract

The photocleavage of homodimeric quinone oxetanes evolves through a non-adiabatic process, the opposite of what has been observed with heterodimeric oxetanes. This is explained by ultrafast transient absorption spectroscopy and quantum chemistry.

Funder

Universitat de València

Ministerio de Ciencia e Innovación

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CP/D4CP00830H

Reference32 articles.

1. N. J.Turro , V.Ramamurthy and J. C.Scaiano , Modern Molecular Photochemistry of Organic Molecules , University Science Books , Sausalito, California , 2010

2. B.Dinda , Essentials of Pericyclic and Photochemical Reactions , Springer Cham , 2017 , vol. 93, pp. 241–275

3. A. C.Weedon , in Synthetic Organic Photochemistry , ed. W. M. Horspool , Springer US , Boston, MA , 1984 , pp. 61–143

4. K.Kokubo and T.Oshima , in CRC Handbook of Organic Photochemistry and Photobiology , ed W. M. Horspool and F. Lenci , CRC Press Taylor & Francis Group , Boca Ratón , 2003 , vol. 1 & 2

5. UV-induced mutation hotspots occur at DNA damage hotspots