Why Does D2 Bind Better Than H2? A Theoretical and Experimental Study of the Equilibrium Isotope Effect on H2 Binding in a M(η2-H2) Complex. Normal Coordinate Analysis of W(CO)3(PCy3)2(η2-H2)-Reference-Cited by-同舟云学术

Why Does D2 Bind Better Than H2? A Theoretical and Experimental Study of the Equilibrium Isotope Effect on H2 Binding in a M(η2-H2) Complex. Normal Coordinate Analysis of W(CO)3(PCy3)2(η2-H2)

Published:1997-10-01 Issue:39 Volume:119 Page:9179-9190
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Bender Bruce R.¹,Kubas Gregory J.¹,Jones Llewellyn H.¹,Swanson Basil I.¹,Eckert Juergen¹,Capps Kenneth B.¹,Hoff Carl D.¹

Affiliation:

1. Contribution from Catalytica Inc., 430 Ferguson Drive, Mountain View, California 94043, Los Alamos National Laboratory, MS-J514, Los Alamos, New Mexico 87545, and the Department of Chemistry, University of Miami, Coral Gables, Florida 33124

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja971009c

Reference44 articles.

1. Secondary .beta.-deuterium isotope effects on the rates and equilibria of organometallic oxidative addition/reductive elimination reactions

2. Mechanistic study of the oxidative addition of dihydrogen to tetrakis(trimethylphosphine)diiodotungsten: observation of an inverse equilibrium isotope effect

3. Theoretical study of primary and secondary deuterium equilibrium isotope effects for hydrogen and methane addition to iridium complex trans-Ir(PR3)2(CO)X

4. NMR spectra and the products of interaction of iridium monohydrides IrHCl2L2 (LP(CH(CH3)2)3 and P(c-C6H11)3) with molecular hydrogen

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