On the Origin of Higher Rotational Barriers in Thioamides than in Amides. Remote Substituent Effects on the Conformational Stability of the Thioamide Group in Thioacetanilides
Author:
Affiliation:
1. Department of Chemistry, University of Sofia, Sofia 1164, Bulgaria
Publisher
American Chemical Society (ACS)
Subject
Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jp034919r
Reference48 articles.
1. Theory Supplemented by Experiment. Electronic Effects on the Rotational Stability of the Amide Group in p-Substituted Acetanilides
2. Vibrational spectra and geometrical isomerism in amides
3. Conformational isomerism of the amide group - a review of the IR and NMR spectroscopic evidence
4. Ultraviolet resonance Raman studies of trans and cis peptides: photochemical consequences of the twisted .pi.* excited state
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