Stable π-Extended Thio[7]helicene-Based Diradical with Predominant Through-Space Spin

Stable π-Extended Thio[7]helicene-Based Diradical with Predominant Through-Space Spin–Spin Coupling

Published:2024-03-06 Issue:11 Volume:146 Page:7480-7486
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Wu Hao¹,Hanayama Hiroki²,Coehlo Max³,Gu Yanwei¹⁴^ORCID,Wu Ze-Hua¹,Takebayashi Satoshi⁵^ORCID,Jakob Gerhard⁶^ORCID,Vasylevskyi Serhii⁷,Schollmeyer Dieter⁸,Kläui Mathias⁶,Pieters Grégory³^ORCID,Baumgarten Martin¹,Müllen Klaus¹⁸^ORCID,Narita Akimitsu¹²^ORCID,Qiu Zijie¹⁹^ORCID

Affiliation:

1. Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany

2. Organic and Carbon Nanomaterials Unit, Okinawa Institute of Science and Technology Graduate University, 1919-1 Tancha, Onna-son, Kunigami-gun, Okinawa 904-0495, Japan

3. Université Paris-Saclay, CEA, INRAE, Département Médicaments et Technologies pour la Santé (DMTS), SCBM, F-91191 Gif-sur-Yvette, France

4. Ningbo Institute of Materials Technology & Engineering, Chinese Academy of Sciences, Ningbo, Zhejiang 315201, P. R. China

5. Science and Technology Group, Okinawa Institute of Science and Technology Graduate University, 1919-1 Tancha, Onna-son, Kunigami-gun, Okinawa 904-0495, Japan

6. Institute of Physics, Johannes Gutenberg University Mainz, Staudinger Weg 7, 55128 Mainz, Germany

7. Engineering Section, Research Support Division, Okinawa Institute of Science and Technology Graduate University, 1919-1 Tancha, Onna-son, Kunigami-gun, Okinawa 904-0495, Japan

8. Department of Chemistry, Johannes Gutenberg University Mainz, Duesbergweg 10-14, 55128 Mainz, Germany

9. School of Science and Engineering, Shenzhen Institute of Aggregate Science and Technology, The Chinese University of Hong Kong, Shenzhen (CUHK-Shenzhen), Guangdong 518172, P.R. China

Funder

Chinese University of Hong Kong, Shenzhen

Deutsche Forschungsgemeinschaft

Johannes Gutenberg-Universit?t Mainz

Science, Technology and Innovation Commission of Shenzhen Municipality

Max-Planck-Gesellschaft

Okinawa Institute of Science and Technology Graduate University

Shenzhen Key Laboratory of Functional Aggregate Materials

Publisher

American Chemical Society (ACS)

Link

https://pubs.acs.org/doi/pdf/10.1021/jacs.3c12840