Measurement of the Rate Constant for H• Abstraction from Methylisobutyryl Radical by (C5Ph5)Cr(CO)3•-Reference-Cited by-同舟云学术

Measurement of the Rate Constant for H• Abstraction from Methylisobutyryl Radical by (C5Ph5)Cr(CO)3•

Published:2006-10-25 Issue:24 Volume:39 Page:8236-8240
ISSN:0024-9297
Container-title:Macromolecules
language:en
Short-container-title:Macromolecules

Author:

Tang Lihao¹,Norton Jack R.¹

Affiliation:

1. Department of Chemistry, Columbia University, 3000 Broadway, New York, New York 10027

Publisher

American Chemical Society (ACS)

Subject

Materials Chemistry,Inorganic Chemistry,Polymers and Plastics,Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/ma0615755

Reference25 articles.

1. Catalytic Chain Transfer in Free-Radical Polymerizations

2. Complex Ions. VI. The Magnetic Moments of Some Iron(III) Complex Ions1

3. There is evidence that the H•transfer rate constant between (C5Ph5)Cr(CO)3H and a vinyl-terminated macromonomer decreases as the chain length increases. See: Tang, L. Scope and Mechanism of Chain Transfer Catalysis with Metalloradicals and Metal Hydrides. Ph.D. Thesis, Columbia University, New York, 2005.

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