Geodesic Polyarenes by Flash Vacuum Pyrolysis
Author:
Affiliation:
1. Merkert Chemistry Center, Boston College, Chestnut Hill, Massachusetts 02467
Publisher
American Chemical Society (ACS)
Subject
General Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/cr050553y
Reference87 articles.
1. The compression of interior bonds can be seen in the calculated transition states for bowl-to-bowl inversions of such geodesic polyarenes.3-5It was a discussion of this phenomenon that evolved into a friendly game of designing ground state molecules with “squeezed bonds”, the outcome of which has recently been published.6,7
2. Corannulene bowl-to-bowl inversion is rapid at room temperature
3. Synthesis and dynamics of the corannulene nucleus
4. Dicyclobuta[de,ij]naphthalene and Dicyclopenta[cd,gh]pentalene: A Theoretical Study
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