Are There Metal Oxides That Prefer a [2 + 2] Addition over a [3 + 2] Addition to Olefins? Theoretical Study of the Reaction Mechanism of LReO3 Addition (L = O-, Cl, Cp) to Ethylene1
Author:
Affiliation:
1. Contribution from Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Strasse, D-35032 Marburg, Germany
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja9829362
Reference38 articles.
1. N-Heterocyclic Carbene, Silylene, and Germylene Complexes of MCl (M = Cu, Ag, Au). A Theoretical Study1
2. Temperatureffekte bei der asymmetrischen Dihydroxylierung: Hinweise auf einen schrittweisen Mechanismus
3. The origin of high enantioselectivity in the dihydroxylation of olefins using osmium tetraoxide and cinchona alkaloid catalysts
4. Theoretische Untersuchungen schließen eine [2 + 2]-Addition als einleitenden Schritt der Osmiumtetroxid-katalysierten Dihydroxylierung von Alkenen aus
5. Theory Does Not Support an Osmaoxetane Intermediate in the Osmium-Catalyzed Dihydroxylation of Olefins
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