Catalytic Enantioselective Allyl- and Crotylboration of Aldehydes Using Chiral Diol•SnCl4 Complexes. Optimization, Substrate Scope and Mechanistic Investigations

Author:

Rauniyar Vivek1,Zhai Huimin1,Hall Dennis G.1

Affiliation:

1. Department of Chemistry, University of Alberta, Edmonton, Alberta T6G 2G2, Canada

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Reference94 articles.

1. For reviews, see:aDenmark, S. E. and Almstead, N. G.InModern Carbonyl Chemistry;Otera, J., Ed.Wiley-VCH:Weinheim, 2000; Chapter10, pp299−402

2. bChemler, S. R. and Roush, W. R.InModern Carbonyl Chemistry;Otera, J., Ed.Wiley-VCH:Weinheim, 2000; Chapter 11,403−490

3. Selective reactions using allylic metals

4. dHelmchen, G., Hoffmann, R., and Mulzer, J.;Schaumann, E.InStereoselective Synthesis. Methods of Organic Chemistry (Houben-Weyl),21st ed.ThiemeStuttgart: New York, 1996; Vol3, pp1357−1602

5. Catalytic Enantioselective Addition of Allylic Organometallic Reagents to Aldehydes and Ketones

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