Solution Conformational Features of the Unsymmetrical Metalla Crown Ether cis-Mo(CO)4{2-(2,2‘-O2C12H8)PO(CH2CH2O)2- 2-C20H12-2‘-OP(2,2‘-O2C12H8)} from 2D NMR Spectroscopy and Molecular Modeling-Reference-Cited by-同舟云学术

Solution Conformational Features of the Unsymmetrical Metalla Crown Ether cis-Mo(CO)4{2-(2,2‘-O2C12H8)PO(CH2CH2O)2- 2-C20H12-2‘-OP(2,2‘-O2C12H8)} from 2D NMR Spectroscopy and Molecular Modeling

Published:2000-03-01 Issue:7 Volume:19 Page:1232-1238
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Hariharasarma Maheswaran¹,Watkins Charles L.¹,Gray Gary M.¹

Affiliation:

1. Department of Chemistry, CHEM201, The University of Alabama at Birmingham, 901 14th Street South, Birmingham, Alabama 35294-1240

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om9906969

Reference32 articles.

1. Chelating phosphinite complexes of Group 6 metal carbonyls with crown-ether-type characteristics. Effect of preferential cation binding on the reactivity of coordinated carbon monoxide

2. Stereochemical studies of a multifunctional P-donor ligand capable of selective lithium ion binding for CO activation via ‘tripodal O3N unit’

3. Complexes of a “mono-p-donor crown ether” hybrid ligand with potential for the activation of a coordinated carbon monoxide via selective cation binding

4. Phosphorus donor-crown ether hybrid ligands as a route to carbonyl activation: phosphorus substituent effects and the importance of strong cation binding

5. Synthesis and chemistry of chelating phosphinite complexes of Group 6 metal carbonyls with crown ether and aza-crown ether characteristics. The effect of preferential lithium cation binding by the product molecule on the reactivity of coordinated carbon monoxide

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