X-ray Crystal and NMR Structure of a Highly Reactive Bidentate 1,2-Diamine−OsO4 Complex, Formally a 20-Electron Outer Valence Shell Species. Mechanistic Implications for the 1,2-Diamine-Accelerated Dihydroxylation of Olefins by OsO4-Reference-Cited by-同舟云学术

X-ray Crystal and NMR Structure of a Highly Reactive Bidentate 1,2-Diamine−OsO4 Complex, Formally a 20-Electron Outer Valence Shell Species. Mechanistic Implications for the 1,2-Diamine-Accelerated Dihydroxylation of Olefins by OsO4

Published:1996-01-01 Issue:33 Volume:118 Page:7851-7852
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Corey E. J.¹,Sarshar Sepehr¹,Azimioara Mihai D.¹,Newbold Ronald C.¹,Noe Mark C.¹

Affiliation:

1. Department of Chemistry, Harvard University Cambridge, Massachusetts, 02138

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja960536d

Reference13 articles.

1. ASYMMETRIC OXIDATION OF OLEFINS WITH OSMIUM TETROXIDE COORDINATED BY CHIRAL DIAMINES DERIVED FROM L-TARTARIC ACID

2. Asymmetric oxidation of olefins to vicinal diols with osmium tetroxide

3. Enantioface differentiation in cis dihydroxylation of carbon-carbon double bonds by osmium tetroxide using a chiral diamine with D2 symmetry

4. Asymmetric dihydroxylation of alkenes with osmium tetroxide: chiral N,N′-dialkyl-2,2′-bipyrrolidine complex

5. Enantioselective vicinal hydroxylation of terminal and E-1,2-disubstituted olefins by a chiral complex of osmium tetroxide. An effective controller system and a rational mechanistic model

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