Controlling the Cleavage of Carbon–Carbon Bonds To Generate α,α-Difluorobenzyl Carbanions for the Construction of Difluoromethylbenzenes-Reference-Cited by-同舟云学术

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Controlling the Cleavage of Carbon–Carbon Bonds To Generate α,α-Difluorobenzyl Carbanions for the Construction of Difluoromethylbenzenes

Published:2019-08-26 Issue:18 Volume:84 Page:11665-11675
ISSN:0022-3263
Container-title:The Journal of Organic Chemistry
language:en
Short-container-title:J. Org. Chem.

Author:

Khatri Hari R.¹,Han Changho²,Luong Erica³,Pan Xiaoliang³^ORCID,Adam Amna T.¹,Alshammari Maali D.¹,Shao Yihan³^ORCID,Colby David A.¹^ORCID

Affiliation:

1. Department of BioMolecular Sciences, University of Mississippi, University, Mississippi 38677, United States

2. Department of Medicinal Chemistry and Molecular Pharmacology, Purdue University, West Lafayette, Indiana 47907, United States

3. Department of Chemistry and Biochemistry, University of Oklahoma, Norman, Oklahoma 73019, United States

Funder

National Institute on Aging

National Institute of General Medical Sciences

Purdue University

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.joc.9b01595

Reference48 articles.

1. Deconstructive diversification of cyclic amines

2. Cleaving carbon–carbon bonds by inserting tungsten into unstrained aromatic rings

3. Carbonylative C−C Bond Activation of Electron-Poor Cyclopropanes: Rhodium-Catalyzed (3+1+2) Cycloadditions of Cyclopropylamides

4. Total Synthesis of (−)-Xishacorene B from (R)-Carvone Using a C–C Activation Strategy

5. Enantioselective Ruthenium-Catalyzed Benzocyclobutenone–Ketol Cycloaddition: Merging C–C Bond Activation and Transfer Hydrogenative Coupling for Type II Polyketide Construction

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2. Transient Formation of Hemiketals from Pentafluoro-gem-diols in the Presence of Alcohols;Journal of Fluorine Chemistry;2023-08

3. Defluoroalkylation of Trifluoromethylarenes with Hydrazones: Rapid Access to Benzylic Difluoroarylethylamines;Organic Letters;2023-02-27

4. Nucleophilic strategies to construct –CF₂– linkages using borazine-CF₂Ar reagents;Chemical Communications;2022

5. Organocatalytic difluorobenzylation of 1,2-diketones via mild cleavage of carbon–carbon bonds;Organic Chemistry Frontiers;2022

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