Kinetic Solvent Effects on the Reactions of the Cumyloxyl Radical with Tertiary Amides. Control over the Hydrogen Atom Transfer Reactivity and Selectivity through Solvent Polarity and Hydrogen Bonding
Author:
Affiliation:
1. Dipartimento di Scienze e Tecnologie Chimiche, Università “Tor Vergata”, Via della Ricerca Scientifica 1, I-00133 Rome, Italy
Funder
Ministero dell'Istruzione, dell'Università e della Ricerca
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jo5026767
Reference57 articles.
1. Advances in Radical-Trapping Antioxidant Chemistry in the 21st Century: A Kinetics and Mechanisms Perspective
2. Kinetics of Hydrogen Atom Abstraction from Substrate by an Active Site Thiyl Radical in Ribonucleotide Reductase
3. Reversible H Atom Abstraction Catalyzed by the Radical S-Adenosylmethionine Enzyme HydG
4. Oxygenase-Catalyzed Desymmetrization ofN,N-Dialkyl-piperidine-4-carboxylic Acids
5. Paramagnetic Intermediates Generated by Radical S-Adenosylmethionine (SAM) Enzymes
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