Reactions of [H2Os3(CO)10] with Conjugated Diynes (RC2C2R‘) Containing Nucleophilic Oxygen in β Position of a Substituent (R = Ph, R‘ = CH2OH, C(O)Ph; R = R‘ = CMe2(OH))
Author:
Affiliation:
1. Inorganic Chemistry, Chemical Center, Lund University, Box 124, SE-221 00 Lund, Sweden
2. Lash Miller Chemical Laboratories, University of Toronto, 80 St. George Street, Toronto, Ontario, Canada M5S 3H6
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om0304107
Reference46 articles.
1. Oxidative addition of 1,3-diynes at triosmium clusters with cleavage of the central carbon–carbon bond: X-ray crystal structure of [Os3(µ3,η2-C2Ph)(µ-C2Ph)(CO)9] derived from 1,4-diphenylbuta-1,3-diyne
2. Tailored synthesis of hydrocarbon chains via carbon-carbon coupling reactions of diynes and alkynes on the square face of a ruthenium Ru4P cluster
3. Conversion of the clusters [Os3(1,3-diyne)(CO)10] into bis(alkynyl) clusters by carboncarbon bond cleavage
4. Enyne and Butatriene Ligands from the Reaction of Diynes on the Square Face of the Hydrido Phosphinidene Cluster (.mu.-H)2Ru4(CO)12(.mu.3-PPh)
5. From butadiynyl (–CC–CCR) ligands to alkylidyne–carbides: synthesis and characterisation of the unusual hexanuclear ruthenium carbido clusters [Ru6(CO)13(µ-CO)2(µ-PPh2)(µ5-C)(µ3-C–CCR)](R = But, Ph)
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