Synthesis, Structural Studies, and Magnetic Exchange Interactions in Low-Valent Manganese Alkoxide Cubes
Author:
Affiliation:
1. Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, and Dipartimento di Chimica, Universitá degli Studi di Firenze, Firenze, Italy 50144
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic951448h
Reference37 articles.
1. X-Ray structural analysis of a tetra-manganess(II) complex of a new (4 × 4) Schiff-base macrocycle incorporating a cubane-like Mn4(alkoxy)4core
2. Formation of a (4 + 4) Schiff-base macrocyclic ligand by a template rearrangement. Crystal and molecular structures of two tetranuclear manganese(II) complexes
3. Neutral catecholate derivatives of manganese and iron: synthesis and characterization of the metal-oxygen cubane-like species M4(DBCat)4(py)6 (M = Mn, Fe), the trinuclear complex Mn3(DBCat)4(py)4, and the dimers M2(DBCat)2(py)n (M = Mn, n = 6; M = Fe, n = 4,6)
4. [Fe4Te4(SPri)4]2–and [Fe4Te4(SPri)4]3–, novel Fe4Te4cluster complexes in different metal oxidation states and [Mn4Te4(TePri)4]4–, the first chalcogenide cubane cluster containing divalent metal ions
5. High-Spin Molecules: Iron(III) Incorporation into [Mn12O12(O2CMe)16(H2O)4] To Yield [Mn8Fe4O12(O2CMe)16(H2O)4] and Its Influence on the S = 10 Ground State of the Former
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