Suppression of Chain Transfer in Catalytic Acrylate Polymerization via Rapid and Selective Secondary Insertion
Author:
Affiliation:
1. Chair of Chemical Materials Science, Department of Chemistry, University of Konstanz, Universitätsstrasse 10, 78457 Konstanz, Germany
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/jacs.5b00179
Reference35 articles.
1. Mechanistic Studies of the Palladium-Catalyzed Copolymerization of Ethylene and α-Olefins with Methyl Acrylate
2. Copolymerization of Ethylene and Propylene with Functionalized Vinyl Monomers by Palladium(II) Catalysts
3. Palladium catalysed copolymerisation of ethene with alkylacrylates: polar comonomer built into the linear polymer chainElectronic supplementary information (ESI) available: NMR data for entries 1, 9, 10, 12 and size exclusion chromatographic data for entries 1, 3, 8, 12. See http://www.rsc.org/suppdata/cc/b1/b111252j/
4. Transition-Metal-Catalyzed Functional Polyolefin Synthesis: Effecting Control through Chelating Ancillary Ligand Design and Mechanistic Insights
5. Ortho-Phosphinobenzenesulfonate: A Superb Ligand for Palladium-Catalyzed Coordination–Insertion Copolymerization of Polar Vinyl Monomers
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