Mechanism of Anion-Catalyzed C–H Silylation Using TMSCF3: Kinetically-Controlled CF3-Anionoid Partitioning As a Key Parameter-Reference-Cited by-同舟云学术

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Mechanism of Anion-Catalyzed C–H Silylation Using TMSCF3: Kinetically-Controlled CF3-Anionoid Partitioning As a Key Parameter

Published:2021-02-22 Issue:5 Volume:11 Page:3017-3025
ISSN:2155-5435
Container-title:ACS Catalysis
language:en
Short-container-title:ACS Catal.

Author:

García-Domínguez Andrés¹,Helou de Oliveira Pedro H.¹,Thomas Gilian T.¹,Sugranyes Arnau R.¹,Lloyd-Jones Guy C.¹^ORCID

Affiliation:

1. EaStChem, University of Edinburgh, Joseph Black Building, David Brewster Road, Edinburgh EH9 3FJ, United Kingdom

Funder

FP7 Ideas: European Research Council

Fundaci?n Banco Santander

Seventh Framework Programme

Mitacs

AGUAR

Schweizerischer Nationalfonds zur Foerderung der Wissenschaftlichen Forschung

Publisher

American Chemical Society (ACS)

Subject

Catalysis,General Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acscatal.1c00033

Reference74 articles.

1. Trifluoromethyltrimethylsilane: Nucleophilic Trifluoromethylation and Beyond

2. Recent advances in the trifluoromethylation methodology and new CF3-containing drugs

3. Perfluoroalkylation with Organosilicon Reagents

4. Controllable double CF2-insertion into sp2 C–Cu bond using TMSCF3: a facile access to tetrafluoroethylene-bridged structures

5. From C 1 to C 3 : Copper‐Catalyzed gem ‐Bis(trifluoromethyl)olefination of α‐Diazo Esters with TMSCF 3

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3. Speciation and kinetics of fluoride transfer from tetra-n-butylammonium difluorotriphenylsilicate (‘TBAT’);Chemical Science;2024

4. Making Full Use of TMSCF₃: Deoxygenative Trifluoromethylation/Silylation of Amides;Chinese Journal of Organic Chemistry;2024

5. TMSCF₃-Mediated Conversion of Salicylates into α,α-Difluoro-3-coumaranones: Chain Kinetics, Anion-Speciation, and Mechanism;The Journal of Organic Chemistry;2023-12-02

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