Unintuitive Inverse Dependence of the Apparent Turnover Frequency on Precatalyst Concentration: A Quantitative Explanation in the Case of Ziegler-Type Nanoparticle Catalysts Made from [(1,5-COD)Ir(μ-O2C8H15)]2 and AlEt3-Reference-Cited by-同舟云学术

Unintuitive Inverse Dependence of the Apparent Turnover Frequency on Precatalyst Concentration: A Quantitative Explanation in the Case of Ziegler-Type Nanoparticle Catalysts Made from [(1,5-COD)Ir(μ-O2C8H15)]2 and AlEt3

Published:2015-04-30 Issue:6 Volume:5 Page:3342-3353
ISSN:2155-5435
Container-title:ACS Catalysis
language:en
Short-container-title:ACS Catal.

Author:

Crooks Adam B.¹,Yih Kuang-Hway¹,Li Long²³,Yang Judith C.²,Özkar Saim⁴,Finke Richard G.¹

Affiliation:

1. Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523, United States

2. University of Pittsburgh, Pittsburgh, Pennsylvania 15261, United States

3. RJ Lee Group, Inc., 350 Hochberg Road, Monroeville, Pennsylvania 15146, United States

4. Department of Chemistry, Middle East Technical University, 06800 Ankara, Turkey

Publisher

American Chemical Society (ACS)

Subject

Catalysis,General Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acscatal.5b00347

Reference53 articles.

1. Ziegler-type hydrogenation catalysts made from group 8–10 transition metal precatalysts and AlR3 cocatalysts: A critical review of the literature

2. Model Ziegler-Type Hydrogenation Catalyst Precursors, [(1,5-COD)M(μ-O2C8H15)]2 (M = Ir and Rh): Synthesis, Characterization, and Demonstration of Catalytic Activity En Route to Identifying the True Industrial Hydrogenation Catalysts

3. Industrial Ziegler-Type Hydrogenation Catalysts Made from Co(neodecanoate)2 or Ni(2-ethylhexanoate)2 and AlEt3: Evidence for Nanoclusters and Sub-Nanocluster or Larger Ziegler-Nanocluster Based Catalysis

4. Iridium Ziegler-Type Hydrogenation Catalysts Made from [(1,5-COD)Ir(μ-O2C8H15)]2 and AlEt3: Spectroscopic and Kinetic Evidence for the Irn Species Present and for Nanoparticles as the Fastest Catalyst

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