Sunlight-Driven Photocatalytic Degradation of Methyl Orange Based on Bismuth Ferrite (BiFeO3) Heterostructures Composed of Interconnected Nanosheets

Author:

Ruby S.1,Rosaline D. Rani2,Inbanathan S. S. R.3,Anand K.4,Kavitha G.5,Srinivasan R.6,Umar Ahmad7,Hegazy H. H.8,Algarni Hamed8

Affiliation:

1. Post Graduate and Research Department of Physics, The American College, Madurai 625002, India

2. Post Graduate and Research Department of Chemistry, Lady Doak College, Madurai 625002, India

3. Mother Teresa Women’s University, Kodaikanal 624102, India

4. Discipline of Medical Biochemistry, School of Laboratory of Medicine and Medical Sciences, College of Health Science, University of KwaZulu-Natal, Durban 4013, South Africa

5. Post Graduate and Research Department of Physics, A.M. Jain College University of Madras, Chennai 600114, India

6. Tamil Nadu Science Council for Science & Technology, Chennai 600025, India

7. Department of Chemistry, Faculty of Arts and Sciences and Promising Center for Sensors and Electronic Devices (PCSED), Najran University, Najran-11001, Saudi Arabia

8. Department of Physics, Faculty of Science, King Khalid University, P.O. Box 9004, Abha, Saudi Arabia

Abstract

Herein, we report the facile microwave-assisted synthesis, characterization and photocatalytic degradation applications of Bismuth ferrite heterostructures composed of interconnected nanosheets (BHNs). The synthesized materials were subjected to several analytical studies such as scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), energy dispersive spectroscopy (EDS), Fourier transform infrared (FTIR) spectroscopy and UV-visible spectroscopy in order to examine the morphological, structural, optical and photo catalytic properties. The structural and morphological characterizations confirmed the rhombohedral perovskite crystal structure and the formation of heterostructures composed of interconnected nanosheets for the synthesized material. The compositional characterization revealed that the synthesized material is bismuth ferrite with high purity. The BHNs were further used as efficient photocatalyst for the photocatalytic degradation of highly hazardous pollutant methyl orange under sunlight irradiation. The sunlight driven photocatalytic experiments revealed ~86% photodegradation of methyl orange dye in 150 min. The presented work revealed that the synthesized BHNs are excellent material for the photocatalytic degradation of various organic contaminants and hazardous pollutants.

Publisher

American Scientific Publishers

Subject

Condensed Matter Physics,General Materials Science,Biomedical Engineering,General Chemistry,Bioengineering

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