Affiliation:
1. G.B. Elyakov Pacific Insitute Bioorganic Chemistry Far East Branch Russian Academy of Sciences
Abstract
A bromine-containing naphthoquinone-carbohydrate conjugate was obtained for the first time by intramolecular condensation of 3-acetylthioglucoside of 6-bromo-2-methoxy-1,4-naphthoquinone under sodium methoxide/ methanol treatment. It has been established that the heterocyclization reaction is accompanied by the substitution of the thioglucoside substituent by the methoxyl group and the formation of an isomeric conjugate.
Publisher
The Russian Academy of Sciences