Modification of Pillared Intercalated Montmorillonite Clay as Heterogeneous Pd Catalyst Supports

Author:

Sun Kailang1,Liu Yonghong1,Zhang Taojun1,Zhou Jie1,Chen Jinyang1,Ren Xiaorong1,Yang Zhen1,Zeng Minfeng1ORCID

Affiliation:

1. Research Center of Advanced Catalytic Materials & Functional Molecular Synthesis, Zhejiang Key Laboratory of Alternative Technologies for Fine Chemicals Process, College of Chemistry & Chemical Engineering, Shaoxing University, Shaoxing 312000, China

Abstract

Montmorillonite clay was modified by pillaring with AlMn oxides in different Al/Mn ratios and intercalation of two kinds of N-containing polymers (i.e., chitosan (CS) and polyvinyl pyrrolidinone (PVP)) chains. The modified pillared montmorillonite clay (PM) showed a rich two-dimensional layered porous structure with tunable parameters, such as large interlayer spacing, high specific area, and large porous volume. They were then used as supports for Pd nanoparticles. As applied in coupling reactions of aryl halides with terminal alkynes, Pd@CS/AlMn-PM showed better comprehensive catalytic performance than Pd@PVP/AlMn-PM. This was mainly attributed to its higher specific area, stronger chelation to Pd species, and better solvent resistance.

Funder

Shaoxing Key Science and Technology Innovation Team Project

Publisher

MDPI AG

Subject

Chemistry (miscellaneous),Analytical Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Molecular Medicine,Drug Discovery,Pharmaceutical Science

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