Nacre-like Anisotropic Multifunctional Aramid Nanofiber Composites for Electromagnetic Interference Shielding, Thermal Management, and Strain Sensing

Author:

Dong Jin1,Lin Jing1ORCID,Zhang Hebai1,Wang Jun1,Li Ye1,Pan Kelin1,Zhang Haichen2ORCID,Hu Dechao2ORCID

Affiliation:

1. School of Applied Physics and Materials, Wuyi University, Jiangmen 529020, China

2. School of Materials and Energy, Foshan University, Foshan 528000, China

Abstract

Developing multifunctional flexible composites with high-performance electromagnetic interference (EMI) shielding, thermal management, and sensing capacity is urgently required but challenging for next-generation smart electronic devices. Herein, novel nacre-like aramid nanofibers (ANFs)-based composite films with an anisotropic layered microstructure were prepared via vacuum-assisted filtration and hot-pressing. The formed 3D conductive skeleton enabled fast electron and phonon transport pathways in the composite films. As a result, the composite films showed a high electrical conductivity of 71.53 S/cm and an outstanding thermal conductivity of 6.4 W/m·K when the mass ratio of ANFs to MXene/AgNWs was 10:8. The excellent electrical properties and multi-layered structure endowed the composite films with superior EMI shielding performance and remarkable Joule heating performance, with a surface temperature of 78.3 °C at a voltage of 2.5 V. Additionally, it was found that the composite films also exhibited excellent mechanical properties and outstanding flame resistance. Moreover, the composite films could be further designed as strain sensors, which show great promise in monitoring real-time signals for human motion. These satisfactory results may open up a new opportunity for EMI shielding, thermal management, and sensing applications in wearable electronic devices.

Funder

Guangdong Basic and Applied Basic Research Foundation

National Natural Science Foundation of China

Innovation and Entrepreneurship Training Program for Wuyi university

Publisher

MDPI AG

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