Preparation and Characterization of Bilayer Polymer-Dispersed Liquid Crystals Doped with Gd2O3 Nanoparticles and Rhodamine B Base Fluorescent Dye

Author:

Wu Yongle12,Zhao Yuzhen1,Li Xun1,Gao Hong3,Guo Zhun1,Wang Dong2ORCID,Luan Yi2ORCID,Wang Lei4ORCID

Affiliation:

1. Xi’an Key Laboratory of Advanced Photo-Electronics Materials and Energy Conversion Device, School of Electronic Information, Xijing University, Xi’an 710123, China

2. Department of Materials Physics and Chemistry, School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China

3. Division of Material Engineering, China Academy of Space Technology, Beijing 100094, China

4. Key Laboratory of Chemical Additives for China National Light Industry, Shaanxi Key Laboratory of Chemical Additives for Industry, College of Chemistry & Chemical Engineering, Shaanxi University of Science & Technology, Xi’an 710021, China

Abstract

Using the polymerization-induced phase separation (PIPS) method, bilayer polymer-dispersed liquid crystal (PDLC) films with a PDLC-PVA-PDLC structure were prepared in this work. It was found that all PDLC performance indexes were affected by polymer mesh size after comparing the microscopic morphology and electro-optical properties of samples with different monomer ratios. Gd2O3 nanoparticles and rhodamine B base fluorescent dyes introduced into the bilayer PDLC optimized the samples’ electro-optical properties and developed new functionalities. In addition, the bilayer PDLC doped with Gd2O3 and rhodamine B base held excellent progressive driving functions as well as stable durability properties. Samples doped with Gd2O3 nanoparticles and rhodamine B base also produced excellent anti-counterfeiting effects under UV irradiation at different angles, further exploiting the application potential of PDLC.

Funder

Natural Science Basic Research Plan in Shaanxi Province of China

Natural Science Foundation of Shaanxi Provincial Department of Education

Science and technology plan project of Xi’an

National Natural Science Foundation of China

Xi’an Science and Technology Plan Project of Shaanxi Province

Youth Innovation Team of Shaanxi Universities

Publisher

MDPI AG

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