Relationship between Permeability and Structure of CO2-Assisted Polymer Compression Products

Author:

Aizawa Takafumi1ORCID

Affiliation:

1. Research Institute for Chemical Process Technology, National Institute of Advanced Industrial Science and Technology, 4-2-1 Nigatake, Miyagino-ku, Sendai 983-8551, Japan

Abstract

Membrane filters were fabricated from polyethylene terephthalate nonwoven fabrics with an average fiber diameter of 8 μm using the CO2-assisted polymer compression method. The filters were subjected to a liquid permeability test and structural analysis was performed using X-ray computed tomography to evaluate the tortuosity, pore size distribution, and percentage of open pores. Based on the results, filter tortuosity was proposed to be a function of porosity. Pore size estimated from the permeability test and X-ray computed tomography were in rough agreement. The ratio of open pores to all pores was as high as 98.5%, even at a porosity of 0.21. This may be due to the process of exhausting trapped high-pressure CO2 after molding. For filter applications, a high open-pore ratio is desirable since it means that many pores are involved in the fluid flow. The CO2-assisted polymer compression method was found to be suitable for the production of porous materials for filters.

Funder

JSPS KAKENHI

Publisher

MDPI AG

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