Air-Stable and Highly Active Transition Metal Phosphide Catalysts for Reductive Molecular Transformations

Author:

Mitsudome Takato123

Affiliation:

1. Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka 560-8531, Osaka, Japan

2. Innovative Catalysis Science Division, Institute for Open and Transdisciplinary Research Initiatives (ICS-OTRI), Osaka University, Suita 565-0871, Osaka, Japan

3. Precursory Research for Embryonic Science and Technology (PRESTO), Japan Science and Technology Agency (JST), 4-1-8 Honcho, Kawaguchi 333-0012, Saitama, Japan

Abstract

This review introduces transition metal phosphide nanoparticle catalysts as highly efficient and reusable heterogeneous catalysts for various reductive molecular transformations. These transformations include the hydrogenation of nitriles to primary amines, reductive amination of carbonyl compounds, and biomass conversion, specifically, the aqueous hydrogenation reaction of mono- and disaccharides to sugar alcohols. Unlike traditional air-unstable non-precious metal catalysts, these are stable in air, eliminating the need for strict anaerobic conditions or pre-reduction. Moreover, when combined with supports, metal phosphides exhibit significantly enhanced activity, demonstrating high activity, selectivity, and durability in these hydrogenation reactions.

Funder

JSPS KAKENHI

JST PRESTO

JST-CREST

the Cooperative Research Program of the Institute for Catalysis, Hokkaido University

Publisher

MDPI AG

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