Affiliation:
1. Key Laboratory of Drinking Water Safety and Distribution Technology of Zhejiang Province, College of Civil Engineering and Architecture, Zhejiang University, Hangzhou 310058, China
2. Future Water Laboratory, Innovation Center of Yangtze River Delta, Zhejiang University, Jiaxing 314000, China
Abstract
In this research, the CuFeS2/MXene-modified polyvinylidene fluoride (PVDF) membrane was prepared to activate peroxymonosulfate (PMS) to remove moxifloxacin (MOX) and its morphology; surface functional groups and hydrophilicity were also studied. The parameters of the catalytic membrane/PMS system were optimized, with an optimal loading of 4 mg/cm2 and a PMS dosage of 0.20 mM. High filtration pressure, alkaline conditions, and impurities in water could inhibit MOX removal. After continuous filtration, the removal efficiency of MOX using the catalytic membrane/PMS system and PVDF membrane was 68.2% and 9.9%, respectively. Batch filtration could remove 87.8% MOX by the extra 10 min contact time between the catalytic membrane and solution. During the filtration process, CuFeS2/MXene on the surface of the catalytic membrane activated PMS to produce SO4•−, HO•, and 1O2, and MOX was removed through adsorption and degradation. Taking humic acid (HA) as the model foulant, reversible fouling resistance in the catalytic membrane/PMS system was 22.8% of the PVDF membrane. The catalytic membrane/PMS system weakened the formation of the cake layer by oxidizing HA into smaller pollutants and followed the intermediate blocking cake filtration model. The novelty of this research was to develop a CuFeS2/MXene–PVDF membrane-activated PMS system and explore its application in antibiotics removal.
Funder
National Key R&D Program of China
Zhejiang Provincial Natural Science Foundation of China