Catalytic Properties of the Spinel-Like CuxMn3−xO4 Copper Manganese Oxides—An Overview

Abstract

Copper manganese oxide spinels and related (multiphase) materials with the formula CuxMn3−xO4 are the active catalysts in a wide variety of industrially important processes due to their great diversity in their phase relations, metal ion valence/site distribution, and chemical properties. In this review, we summarize the preparation methods and their effects on the composition, properties, and catalytic properties of various CuxMn3−xO4 catalysts with various Cu/Mn ratios. The main summarized catalytic reactions are the oxidation of carbon monoxide, nitrogen oxide, and hydrogen sulfide and the oxidative removal of organic solvents such as benzene, toluene, and xylene from the air. Some industrially important reactions (steam reforming of methanol or synthesis gas) and the manufacture of organic chemicals (methyl formate, propylene oxide, and benzyl alcohol) catalyzed by CuxMn3−xO4 spinels are also reviewed.