Is a 2D Nanostructured Surface Capable of Changing the Corrosion and Magnetic Properties of an Amorphous Alloy?

Author:

Kuznetsova Irina1,Lebedeva Olga1ORCID,Kultin Dmitry1ORCID,Perova Natalia2,Kalmykov Konstantin1,Chernavskii Petr1,Perov Nikolai2ORCID,Kustov Leonid134

Affiliation:

1. Department of Chemistry, Lomonosov Moscow State University, 119991 Moscow, Russia

2. Faculty of Physics, Lomonosov Moscow State University, 119991 Moscow, Russia

3. N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky Prospect 47, 119991 Moscow, Russia

4. Institute of Ecology and Engineering, National Science and Technology University “MISiS”, Leninsky Prospect 4, 119049 Moscow, Russia

Abstract

In this work, an attempt was made to reveal and explain the influence of the process of formation of 2D nanostructures at the surface of an amorphous alloy (an alloy with the composition Co75Si15Fe5Cr4.5Al0.5 (in at.%) was used for this purpose) on the corrosion and magnetic properties of such an alloy. Two-dimensional nanostructures (nanocells of 100–150 nm in size, which were obtained by anodizing the initial sample in an ionic liquid) are essentially a pattern on the surface of the sample, and they cannot completely cover and block the surface from external effects. It was postulated that the presence of these nanostructures during corrosion and magnetic tests has no significant effect. However, a noticeable inhibition effect was observed during corrosion tests and a less noticeable (but still detectable) effect was observed during magnetic tests. The authors believe that the effect obtained, with a detailed study, can be used to increase the corrosion resistance and to improve the properties of traditional magnetic materials.

Funder

Ministry of Science and Higher Education of the Russian Federation

Russian Science Foundation

Publisher

MDPI AG

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Computer Science Applications,Spectroscopy,Molecular Biology,General Medicine,Catalysis

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