Bis(2,6-di(pyridin-2-yl)pyridin-4-yl)-6,6′-(1,2-diselanediyl)dihexanoate-Reference-Cited by-同舟云学术

Bis(2,6-di(pyridin-2-yl)pyridin-4-yl)-6,6′-(1,2-diselanediyl)dihexanoate

Published:2023-12-20 Issue:1 Volume:2024 Page:M1752
ISSN:1422-8599
Container-title:Molbank
language:en
Short-container-title:Molbank

Author:

Popa Evelyn¹,Andelescu Adelina A.¹^ORCID,Badea Valentin²^ORCID,Svera (m. Ianăşi) Paula³,Szerb Elisabeta I.¹^ORCID

Affiliation:

1. “Coriolan Drăgulescu” Institute of Chemistry, Romanian Academy, 300223 Timisoara, Romania

2. Department of Applied Chemistry and Organic and Natural Compounds Engineering, Politehnica University Timisoara, 300001 Timisoara, Romania

3. National Institute for Research and Development in Electrochemistry and Condensed Matter, 300569 Timisoara, Romania

Abstract

The present paper describes the preparation and characterization of a new dinuclear ligand based on terpyridine featuring a diselenide unit. This new compound was synthesized in a two-step procedure that first involved the insertion of the diselenide moiety on a carboxylic acid and was followed by a Steglich esterification reaction between the biscarboxylic acid containing the diselenide unit and 2,6-di(pyridin-2-yl)pyridin-4-ol (tpyOH). The title compound was characterized via FT-IR, Raman, NMR (1D and 2D), and UV-Vis spectroscopies and elemental analysis. Emission properties were investigated.

Funder

Ministry of Research, Innovation and Digitization, CNCS/CCCDI—UEFISCDI

Publisher

MDPI AG

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

https://www.mdpi.com/1422-8599/2024/1/M1752/pdf

Reference24 articles.

1. Terpyridine-metal complexes: Applications in catalysis and supramolecular chemistry;Wei;Coord. Chem. Rev.,2019

2. Husson, J. (2023). 4′-(N-(2-Cyanoethyl)pyrrol-2-yl)-2,2′:6′,2″-terpyridine. Molbank, 2023.

3. Square-Planar Pd(II), Pt(II), and Au(III) Terpyridine Complexes: Their Syntheses, Physical Properties, Supramolecular Constructs, and Biomedical Activities;Eryazici;Chem. Rev.,2008

4. Terpyridines and their Complexes with First Row Transition Metal Ions: Cytotoxicity, Nuclease Activity and Self-Assembly of Biomacromolecules;Winter;Curr. Top. Med. Chem.,2012

5. Playing with Pt (II) and Zn (II) coordination to obtain luminescent metallomesogens;Andelescu;Chem. Eur. J.,2020