Water-Soluble Biomass Resist Materials Based on Polyglucuronic Acid for Eco-Friendly Photolithography

Author:

Miura Sayaka1ORCID,Hachikubo Yuna1,Yamagishi Rio1ORCID,Ando Mano1,Takei Satoshi12ORCID

Affiliation:

1. Graduate School of Engineering, Toyama Prefectural University, Imizu 939-0398, Toyama, Japan

2. Graduate School of Engineering Science, Osaka University, Toyonaka 560-8531, Osaka, Japan

Abstract

This study presents the development of photolithography employing biomass-based resist materials derived from polyglucuronic acid. Traditional resist materials require coating and developing procedures involving organic solvents, whereas our approach enables the use of water-based spin-coating and developing processes. The water-soluble biomass resist material, derived from polyglucuronic acid, exhibited exceptional photosensitivity at an exposure wavelength of 365 nm and a dose of approximately 90 mJ/cm2. We successfully patterned the microstructures, creating 3 µm lines and 6 µm holes. This organic solvent-free coating process underscores its applicability in scenarios such as in the microfabrication on plastic substrates with limited organic solvent tolerance and surface-patterning biomaterials containing cells and culture components.

Funder

Japan Society for the Promotion of Science Bilateral Joint Research Projects

TOBE MAKI Scholarship Foundation

OSG Foundation

Izumi Science and Technology Foundation

Amano Institute of Technology Foundation

Iketani Science and Technology Foundation

Takeuchi Foundation

Amada Foundation

Ogasawara Foundation

Die and Mould Technology Promotion Foundation

Lotte Foundation

KOSE Cosmetology Research Foundation

Hayashi Rheology Memorial Foundation

Student Support Associations of Cooperation Between Industry and Academia 2023

TAU Scholarship 2023

Marubun Research Promotion Foundation 2023

Publisher

MDPI AG

Subject

Materials Chemistry,Surfaces, Coatings and Films,Surfaces and Interfaces

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