Microstructure and Corrosion Behavior of Fe-Based Austenite-Containing Composite Coatings Using Supersonic Plasma Spraying

Author:

Zhang Xiaoyan12ORCID,Luo Tiegang1,Liu Shenglin2,Zheng Zhibin1,Wang Juan1,Zheng Kaihong1,Wang Shuai1,Chen Huantao1

Affiliation:

1. Institute of New Materials, Guangdong Academy of Sciences, National Engineering Research Center of Powder Metallurgy of Titanium& Rare Metals, Guangdong Provincial Key Laboratory of Metal Toughening Technology and Application, Guangzhou 510650, China

2. School of Materials Science and Engineering, Chang’an University, Xi’an 710061, China

Abstract

The Fe-based austenite-containing composite coatings with various contents (3 vol.%, 6 vol.%, 9 vol.%, 12 vol.%) of austenite powder additions were created by supersonic plasma spraying on 45 steel substrates. The microstructure, phase composition, microhardness, and porosity of the composite coatings were examed. Moreover, special attention was paid to the effect of austenite powder on the corrosion resistance of the austenite-containing composite coatings. The results found that the addition of austenite powders could significantly improve the corrosion resistance of Fe-based coatings, which is mainly due to three correlated phenomena caused by the austenite particles. First, austenite particles significantly reduce the porosity of the austenite-containing composite coatings and form a denser coating structure due to their low melting point and good chemical compatibility with the Fe-based alloy. Further, austenite particles help to refine the grains and increase the grain boundary density. Last but not least, austenite particles help to generate more diffusely distributed second phases in the coating, improving the chemical homogeneity and hardness of the coating.

Funder

GDAS’ Project of Science and Technology Development

National Key Research and Development Program of China

Publisher

MDPI AG

Subject

Materials Chemistry,Surfaces, Coatings and Films,Surfaces and Interfaces

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