Influence of NaAlO2 Concentration on the Characteristics of Micro-Arc Oxidation Coating Fabricated on a ZK60 Magnesium Alloy

Author:

Zhou Shu-Fan1,Lu Sheng1,Lv Wei-Gang1,Wang Ze-Xin1,Oleksandr Dubovyy2,Gu Jun-Jie1,Zhang Jin-Wei1,Chen Liang-Yu1ORCID

Affiliation:

1. School of Material Science and Technology, Jiangsu University of Science and Technology, Zhenjiang 212003, China

2. Department of Material Science and Technology of Metals, Admiral Makarov National University of Shipbuilding Institute, 54025 Nikolaev, Ukraine

Abstract

This study investigated the impact of NaAlO2 concentration in electrolytic solutions on micro-arc oxidation (MAO) coatings, focusing on their surface quality enhancement and corrosion resistance improvement. The surface morphology and microstructure of these coatings were assessed using scanning electron microscopy. Mechanical properties, such as hardness and wear resistance of MAO coatings, were tested. The hardness of the 6 g/L group was 411.2 HV. X-ray photoelectron spectroscopy examinations showed that MgAl2O4, CaMgP2O7, and MgSiO4 were the phases in the MAO coating. Antibacterial assessments were performed to evaluate the influence of NaAlO2 concentration, and the antibacterial rate of the 6 g/L group reached 97.08%. The hydrophilicity of the coatings was determined using water contact angle measurements, wherein the water contact angle of the 6 g/L was the lowest, at 58.25°. Corrosion resistance was evaluated with an electrochemical workstation. The findings revealed that the MAO coatings prepared with a NaAlO2 concentration of 6 g/L exhibited superior uniformity with fewer defects, enhanced corrosion resistance, and increased adhesive strength compared to other concentration groups. The 6 g/L NaAlO2 concentration MAO coating demonstrated the highest fitting coating resistance R3 (8.14 × 104 Ω∙cm2), signifying better corrosion resistance.

Publisher

MDPI AG

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